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The conditional acid dissociation constants (pKa′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pKa′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln−1):
The estimated accuracy of pH measurements using these calculated pKa′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities.  相似文献   
23.
Flower and fruit production of the abundant, tall, long-lived, dioecious, surface-pollinating seagrass species Enhalus acoroides (L.) Royle were estimated at seven sites in the reef flats off Bolinao (NW Luzon, The Philippines) featuring different fragmentation of the seagrass meadows. Fragmentation of the seagrass meadow was quantified as cover of E. acoroides and all seagrass species present in 20×20 m plots. E. acoroides and overall seagrass cover were correlated positively. The proportion of female flowers of E. acoroides that developed a fruit increased sharply as overall seagrass cover was around 50%. Apparent sex ratio bore no relationship with overall seagrass cover. This threshold-type of relationship suggests that fragmentation of seagrass meadows can have a major effect on the reproductive output of this species. A possible mechanism underlying these results would be a non-linear increase of the efficiency of trapping the surface-dispersed pollen with increasing seagrass canopy density. This provides the first evidence based on real data that fragmentation can affect the population dynamics of seagrass species.  相似文献   
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Chromophoric dissolved organic matter (CDOM) is the major light absorber in the Baltic Sea. In this study, excitation emission matrix (EEM) fluorescence spectra and UV–visible absorption spectra of CDOM are reported as a function of salinity. Samples from different locations and over different seasons were collected during four cruises in 2002 and 2003 in the Baltic Sea in both Pomeranian Bay and the Gulf of Gdansk. Absorption by CDOM decreased with increased distance from the riverine source and reached a relatively stable absorption background in the open sea. Regression analysis showed that fluorescence intensity was linearly related to absorption by CDOM at 375 nm and aCDOM(375) absorption coefficients were inversely related to salinity. Analysis of CDOM-EEM spectra indicated that a change in composition of CDOM occurred along the salinity gradient in the Baltic Sea. Analysis of percent contribution of respective fluorophore groups to the total intensity of EEM spectra indicated that the fluorescence peaks associated with terrestrial humic components of the CDOM and total integrated fluorescence decreased with decreasing CDOM absorption. In contrast, the protein-like fraction of CDOM decreased to a lesser degree than the others. Analysis of the percent contribution of fluorescence peak intensities to the total fluorescence along the salinity gradient showed that the contribution of protein-like fluorophores increased from 2.6% to 5.1% in the high-salinity region of the transect. Fluorescence and absorption changes observed in the Baltic Sea were similar to those observed in similar transects that have been sampled elsewhere, e.g. in European estuaries, Gulf of Mexico, Mid-Atlantic Bight and the Cape Fear River plume in the South Atlantic Bight, although the changes in the Baltic Sea occurred over a much smaller salinity gradient.  相似文献   
26.
海底泉在滨海地下水排泄过程中起着重要的作用。本文给出了含有一个海底泉的在海底延伸的越流承压含水层系统中地下水水头在海潮作用下波动的近似解析解。该含水层顶底板隔水且向海底延伸有限距离。假设含水层的海底露头被一层隔水层覆盖,海底泉由一个渗透性很好的完全穿透海底含水层硕板的圆柱体渗漏天窗(海底泉孔)来表示。近似解析解中包含了6个参数:承压含水层的海潮传播参数,海底泉孔中心到海岸线的距离,表示泉的圆柱体的等效半径,海底泉孔中心到含水层海底露头处的距离,承压含水层的海潮载荷效率和弱透水层的越流。分析表明,如果海底泉孔中心到海岸线的距离远大于泉孔的等效半径,且海底泉孔中心到含水层海底露头处的距离远大于泉孔的等效半径时,解析解的近似误差可以忽略。然后本文讨论了解析解的两个基本性质,分析了海底泉对海底地下水水头波动的影响。  相似文献   
27.
张修脉 《山东地质》2008,24(2):18-20
该文分析研究了彩山小流域的区域坡度和土壤特性,并根据区内土壤性质划分出4个小区域,即:自然坡度在20°~25°内为V1区,15°~20°内为V2区,10°~15°内为V3区,5°~10°内为V4区,分别反映了不同的土壤等级及土壤抗冲能力。同时,也研究出了一个系统化、理论化的科学依据i=V(10/3)/5B,并对所有砂石山区水土保持治理工作具有借鉴性和实用性。  相似文献   
28.
对会“打滑”地层,国内外均为难题,新研究的技术是:(1)用特殊的新构思,运用内设备,压制出可批量2供应的高强度金刚石,这种高强度金刚石可承受比目前高得多的钻压;(2)运用强力钻进的配套技术,用上述高强度金刚石制作头。  相似文献   
29.
Some comparisons between mining-induced and laboratory earthquakes   总被引:3,自引:0,他引:3  
Although laboratory stick-slip friction experiments have long been regarded as analogs to natural crustal earthquakes, the potential use of laboratory results for understanding the earthquake source mechanism has not been fully exploited because of essential difficulties in relating seismographic data to measurements made in the controlled laboratory environment. Mining-induced earthquakes, however, provide a means of calibrating the seismic data in terms of laboratory results because, in contrast to natural earthquakes, the causative forces as well as the hypocentral conditions are known. A comparison of stick-slip friction events in a large granite sample with mining-induced earthquakes in South Africa and Canada indicates both similarities and differences between the two phenomena. The physics of unstable fault slip appears to be largely the same for both types of events. For example, both laboratory and mining-induced earthquakes have very low seismic efficiencies where a is the apparent stress and is the average stress acting on the fault plane to cause slip; nearly all of the energy released by faulting is consumed in overcoming friction. In more detail, the mining-induced earthquakes differ from the laboratory events in the behavior of as a function of seismic momentM 0. Whereas for the laboratory events 0.06 independent ofM 0, depends quite strongly onM 0 for each set of induced earthquakes, with 0.06 serving, apparently, as an upper bound. It seems most likely that this observed scaling difference is due to variations in slip distribution over the fault plane. In the laboratory, a stick-slip event entails homogeneous slip over a fault of fixed area. For each set of induced earthquakes, the fault area appears to be approximately fixed but the slip is inhomogeneous due presumably to barriers (zones of no slip) distributed over the fault plane; at constant , larger events correspond to larger a as a consequence of fewer barriers to slip. If the inequality a / 0.06 has general validity, then measurements of a E a /M 0, where is the modulus of rigidity andE a is the seismically-radiated energy, can be used to infer the absolute level of deviatoric stress at the hypocenter.  相似文献   
30.
朱令人 《内陆地震》1993,7(2):90-105
新疆的地震预报是1970年开始的。二十多年来在“边观测、边研究、边预报”、“多路探索、多兵种联合作战”、“走综合预报之路”的方针指导下取得了长足的进展。建设了43个地震台站,投入189套仪器,建成了遍布全疆的地震无线通讯网,开展了历史地震调查和地震烈度区划工作,建立健全了地震会商预报制度,进行了多方面的地震预报研究。实际地震预报统计分析表明,扣除自然发震概率之后,趋势预报的成功率约0.3,短临预报的成功率约0.1。在前兆台网控制范围内取得了一些震例,说明地震确实是有前兆的,但又是非常复杂的。地震预报作为科学难题还有漫长的路要走。作者简要地讨论了地震观测的间接性和地震异常的离散性、难以区别的地震异常和地壳变动异常、建立在复杂现象基础上的地震前兆以及地震的混沌性对地震预报的影响等科学问题。  相似文献   
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